新型三聚氯氰衍生物的合成及其性能.pdf

石油化
?1004
PETROCHIEMIICAL TECHNOLOGY
2013年第42卷第9期
新型三聚氯氰衍生物的合成及其性能
周建华,刘小红2,徐冬梅
(1.中科纳米涂料技术(苏州)有限公司,江苏苏州215024;
2.苏州大学材料与化学化工学部,江苏苏州215123)
摘要]以二氧六环和水为溶剂、以2-氯-4,6-二(2-氧基)-1,3,5-三嗪(CNTA)和1-羟基蒽醌(HYA)为原料,合成了
新型三聚氯氯衍生物1-「4,6-双-(2-茶氧基)-2-[1,3,5]三嗪氧基]蔥醌( DNATA)。考察了原料配比、破的种类和用
量、反应温度、反应时间等反应条件对 DNATA收率的影响,得到了适宜的反应条件。实验结果表明,在NaOH作用下,在
n(HYA):H(NaOH):n(CNTA)=1.1:1.5:1.0、反应温度90℃、反应时间72b的优化条件下, DNATTA收率达90.1%。采用
FTIR、HNMR、MS和元素分析等方法对 DNATA的结构进行了表征。 DNATAI的熔点为198~200℃, DNATAI的分解温度为350
;在四氢呋喃中,最大吸收波长为331mm,摩尔吸光系数为4.96x1L/(mol?cm),最大荧光波长为400nm。
关键词」三聚氯氰衍生物;2-氯-4,6-二(2-萘氧基)-1,3,5-二嗪;1-羟基蔥醌;氢氧化钠;热稳定性
文章编号1]1000-8144(2013)09-1004-05
中图分类号]」TQ242
文献标志码」A
Synthesis and Properties of a Novel Cyanuric Chloride Derivative
Zhou Jianhua, Liu Xiaohong, Xu Dongmei
(1. Suzhou )Zhongke Nanotech Coating Co. LTD, Suzhou Jiangsu 215024, China; 2. College of Chemistry, Chemical
Engineering and Materials Science, Soochow University, Suzhou Jiangsu 215123, China)
Abstract A novel cyanuric chloride derivative 1-[4, 6-bis-(2-naphthyloxy)-1, 3, 5] triazine-2
yloxy anthraquinone(DNATA)was synthesized from 2-chloro-4, 6-bis-(2-naphthyloxy)-[1
triazine(CNTA )and I-hydroxyanthraquinone(HYA with water and dioxane as solvents. The effects of
the mole ratio of the raw materials, type and dosage of bases, and reaction temperature and reaction
time on the yield of DNATA were studied. Under the optimum reaction conditions of sodium hydroxide
as the base, n(HYA): n(sodium hydroxide): n(CNTA) 1.1: 1.5: 1.0, reaction temperature 90
and reaction time 72 h, the yield of DNATA reached 90.1%o. The product structure was characterized
by means of FTIR, H NMR, MS and elementary analysis. Its melting points is in the range of 198
200 C and its decomposition temperature is 350 C. In tetrahydrofuran, its maximum absorption
wavelength, mole extinction coefficient and maximum fluorescence emission wavelength are 33 1
mm,4.96×x10°L/(mol·cm)and400nm, respectivel
Keywords J cyanuric chloride derivative; 2-chloro-4, 6-bis-(2-naphthyloxy)-[1, 3, 5] triazine;
1-hydroxyanthraquinone; sodium hydroxide; thermostability
三聚氯氰分子中含有3个氯原子,它们不但具聚氯氰衍生物的设计合成长期以来备受关注。通过
有类似酰氯的反应活性,而且可通过控制反应条
件使反应分步进行,从而得到各种三聚氯氰衍生[收稿日期12013-02-16:[修改稿日期]2013-07-(8
物3。三聚氯氰衍生物具有良好的光活性、生物
作者简介」問建华(1965-),男,江苏省宜兴市人,大学,T
程师,电话0512-62620330,电邮zih500c163.com。联系人:徐
活性和热稳定性,被广泛用于染料43、农药的
冬梅,电话0512-6582027,电邮xdm,sd@163.com
医药7、助剂?、光电材料9等领域,因此新型
基金项目]国家自然科学基金项目(21074085)。