渤海南部辛基酚和双酚A污染状况研究.pdf

第33卷第2期
海洋通报
Vol. 33 No. 2
2(014年4月
MARINE SCIENCE BULLETIN
Apr.2014
Doi:10.11840/j.issn.1001-6392.2014.02.016
渤海南部辛基酚和双酚A污染状况研究
邓旭修13,黄会1…3,徐英江12,宫向红12,吕振波12
刘慧慧12,张华威1,3,任传博1…3,张秀珍12,4
(1.山东省海洋资源与环境研究院,山东烟合264006;2.山东省海洋生态修复重点实验室,山东烟台264006
3.州烟台山水海产有限公司,山东台264006:4.山东省海洋环境监测站,山东烟台264006)
摘要:硏究采用固相萃取(SPE)-气相色谱-质谱法(GC-MS)对2012年5月份渤海南部表层海水中的辛基酚(OP)和
双酚A(BPA)的污染状况进行了调查。结果表明,渤海南部56个站位表层海水中OP均有检出,浓度范制<1.50-20.1ng/L
平均浓度4.17ng/L,BPA均有检出,浓度范<1.50-275ngL,平均浓度34.8ng/L。OP高浓度分布在漏油事散区Y系列和黄
河口南部、莱州湾西部湾口以及SL20站位,且菜州湾湾口普遍高于湾内:BPA总体分布莱州湾沿岸站位浓度普遍较高。渤
海南部表层海水中OP污染较胶州湾等水体严重,BPA浓度部分站位浓度已达到泥螺胚胎生成的4周10%效应浓度(EC
由此可知,渤海南部已经受到OP和BPA不同程度的污染,有可能对生物带来一定的生态风險。
关键词:辛基酚;双酚A;SPE-GC-MS;表层海水;漏油事枚
中图分类号:X832
文献标识码:A
文章编号:1001-6932(2014)02-0222-06
Survey of Octylphenol and Bisphenol A contamination in
the southern Bohai Sea
DENG Xu-xiu HUANG Hui, XU Ying-jiang, GONG Xiang-hong, LV Zhen-bo,
LIU Hui-hui12 ZHANG Hua-wei1. REN Chuan-b013. ZHANG Xiu-zhen1 2.4
1 Shandong marine Resource and Envionment Research Insti ue Yan a 64006, China Shandong Province Key Laboratory of
Restoration for Marine Ecology, Yantai 264006, China; 3. Yantai Shanshui Seafood CoLtd, Yantai 264006, China: 4. Shangdong Fishery
Environmental Monitoring Station, Yantai 264006, China)
Abstract: Octylphenol (OP)and bisphenol A(BPA)in surface water of the southern Bohai Sea in May 2012 were
anal yzed by SPE-GC-MS in the study. The results showed that OP and BPA were detected in surface water samples of all the
56 stations. The concentration ranges of OP and BPA were from<1.50 to 20.1 ng/L and from <150 to 275 nl, and the
average concentrations were 4.17 ng/ and 34.8 ng/L, respectively. The high concentration areas of OP were in the oil spill
area named Y, to the south of the Yellow River estuary, and to the southwest of the Laizhou Bay and SL20 station. The levels of
OP and BPA in the bay mouth were generally higher than those in the bay water; BPA was concentrated in the coastal area of
the Laizhou Bay, The pollution of OP in the surface water of southern Bohai Sea was more serious than that in the Jiaozhou
Bay, and the concentrations in several stations exceeded the 10 effective concentration(EC) of BPA for embryo
production in Potamop yrgus antipodarum after the exposure of 4 weeks.In general, the southern Bohai Sea was already
polluted by OP and BPA in different levels, which might have potential eco logical risk to the biosystems
Keywords Octy phenol; Bisphenol A; SPE-GC-MS; surface water; oil spill accident
收稿日期:2013-02-28;修订日期:2013-07-05
基金项目:海洋公益性行业科研专项(201105013);水生动物营养与饲料泰川学者岗位(2007-2012);山东省科学技术发展计划项目
(2012GHY11517);烟台市科技发展计划项目(2012134)
作者简介:邓旭修(1984-),男,助理工程师,主要从事持久性污染物监测工作。电子邮箱:Ily100298@163.com
通讯作者:张秀珍(1964-),女,研究员,从事水广品质量安全与标准化。电子邮箱:zXz0535501@126.com。