有机酸掺杂聚苯胺的研究进展.pdf

化
工.
进展
CIIEMIICAL INDUSTRY AND ENGINEERING PROGRESS
2016年第35卷第10期
综述与专论
有机酸掺杂聚苯胺的研究进展
書慧,庞智,高肖汉,雪川,罗冠华,张晓帆,路振华2
辽宁石油化工大学化学化工与环境学部,辽宁抚顺113001:2中国石油独山子石化公同乙烯
新疆克拉玛依833699
摘要:聚苯胺是一种非常有前途的导电聚合物。掺杂能提高聚苯胺的导电性、稳定性及其他性能,聚苯胺的掺
杂受到了人们的广泛关注,尤其是有机酸的掺杂。有机酸种类众多且性能各异,能够使聚苯胺很多性质发生变
化。本文重点综述了分别以单一有机酸、有机酸和金属氧化物、有机酸和无机酸、有机酸和其他无机物为掺杂
剂合成聚苯胺的研究现状,详细介绍了各种掺杂态聚苯胺的性能及应用、简要介绍了影响聚胺性能的因素
并比较了不同掺杂态聚苯胺的优缺点。分析结果表明:与单一有机酸掺杂的聚苯胺相比,采用两种类型的掺杂
剂共掺杂合成的聚胺具有更突出的性能及更大的应用前景。提出了采用两种或两种以上不同类型的掺杂剂共
掺杂将是聚苯胺今后的主要研究方向
关键词:聚苯胺;聚合物;稳定性;有机酸掺杂;合成
中图分类号:1Q316文献标志码:A文章编号:1000-6613(2016)10-3226-10
DOI:10.1608511sSn.1000-6613.2016.10.030
Research progress of organic acids doped polyaniline
CAO Hui, PANG Zhi, G Xiahan, Lxch, LO Gi, ZHANG Xiafan, L Zh n
( College of Chemistry, Chemical Engineering and Environmental Engineering, Liaoning niversity of Petroleum
Chemical Techology, Fushun 113001, Liaoning, China; Ethylene Factory of Petrochina Dushanzi Petrochemical
Company, Petrochina, Kelamayi 833699, Xinjiang, China)
Abstract: Polyaniline is one of the most promising conducting polymers, and doping can improve ils
electrical conductivity, stability and other properties. Therefore, more and more attention has been paid
to the doping of the polyanilinc, especially with organic acid. There arc many kinds organic acid that
have different abilities to change many properties of polyaniline. Research progresses about the
polyaniline doped by single organic acid, organic acid and metal oxide, organic acid and inorganic
acid, organic acid and other inorganic substance were discussed in this paper. The properties and
applications of various kinds of doped polyaniline were presented in detail and the affecting factors on
thc propcrtics of doped polyanilinc wcrc also summarizcd. Thc advantagcs and disadvantages of doped
polyaniline were compared. Compared with the single organic acid doping, polyaniline doped with
co-dopants have more outstanding properties and broader applications. This paper proposed that
co-doping of polyaniline with two or more different kinds of dopants is the main research direction in
thc future
Key words: polyanilinc; polymers; stabilily; organic acid doping; synthesis
收稿日期:2015-12-28:修改稿日期:2016-03-06。
的研究。F-mailchheaohui(a163.com,联系人:吕雪川,博土,教授
基金项目:国家自然科学青年基金(21003069,21103078)及辽宁石
研冗方向为新材料的热力学、新物质、热化学利热分析等:E-mai
油化工大学环境科学与工程学科创新団队项日(120141号
xuechuanster(@163.com
第一作者:曹慧(1989-),女,硕土研究生,主要从事有札合成方面
万方数括